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1999
other natural products
other natural products
U 0800
A General Synthetic Route Towards γ- and δ-Lactones. Total Asym36 - 270 metric Synthesis of (-)-Muricatacin and the Mosquito Oviposition
Pheromone (5R,6S)-6-Acetoxy-hexadecanolide.
— Chiral 5-or
6-membered lactones such as the hexanolide (VIII) or (-)-muricatacin (XI) are
prepared from simple starting materials (I) by reaction sequences involving
reduction, Wittig–Schlosser coupling, Sharpless asymmetric dihydroxylation,
oxidation and lactonization.
— (COULADOUROS, ELIAS A.; MIHOU,
ANASTASIA P.; Tetrahedron Lett. 40 (1999) 26, 4861-4862; Dep. Chem.,
Agric. Univ. Athens, GR-11855 Athens, Greece; EN)
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