Патент USA US2136205
код для вставкиPatented Nov. 8, 1938 2,136,205 UNETED STATES PATNT OFFCE . 2,136,205 BLASTING POWDER Land 8. Byers, Glendale, Calif. No Drawing. Application November 15, 1937, Serial No. 174,694 3 Claims. (C1. 52-11) This invention relates to blasting powder and ably in the form of a ?ne spray to form a slightly has for its object an improvement in explosive compositions suitable for general blasting pur poses which will have important advantages over i black powder. , Among the advantages of my improved powder over blasting powder may be mentioned a lesser density with same heave or moving power, greater rate of decomposition upon explosion, more re 0 sistant to water or moisture, much less subject to ignition from shock or friction, not subject to ignition from contact with ordinary ?ame, no poisonous fumes, and with all cheaper and quicker _ to manufacture. > Briefly described my improved blasting powder may be said to comprise a loose mass of sodium nitrate kernels, each of which is entirely en veloped by an adherent layer of explosive agents adapted to form a substantially balanced forti?ed ) and sensitized entity complete itself, and exhibit ing all of the characteristics above enumerated. My improved blasting powder consists of the following ingredients: sticky film of this explosive material about each pellet of the nitrate. - As soon as the nitrate pellets are evenly coated the previously ?nely powdered and intimately 5 mixed remaining ingredients are dusted in while the rolling is continued until each individual sodium nitrate pellet is completely enveloped and enclosed in a layer of the thoroughly mixed pow dered ingredients evenly distributed thereover, 1.0 and bound thereto so as to form a substantially dry granular mass each grain of which is a‘ com plete explosive unit. ‘ The coating of the nitrate pellets as described should be carried out at a temperature sufficiently 15 above the setting point of the particular liquifiable nitro body being used so that this binding agent will remain in ?uid condition until the comple tion of the coating operation. Instead of the particular nitro bodies set out, 20 others such as the nitro glycerine, benzenes, naphthalenes, etc. may be used, but those given in the formula are preferred. Percent by weight 5 Pelleted sodium nitrate ____________ __ 90 to A liquid nitro body (liqui?able at mod- . crate temperatures) _____________ __ 3 to 80 6 Ammonium nitrate ______________ __'__ 3 to 6 Potassium perchlorate _____________ __ 3* Powdered aluminum _______________ __ 3 to l to 6 2 Also, the speci?c nitrate or perchlorate and oxidizable metal used as the coating layer may 25 be varied within the knowledge of explosive en gineers, but after my experiments I feel that the above simple formula will meet all requirements in a blasting powder of this kind, though any such modi?cations as suggested- are intended to be 30 included in the scope of my appended claims. 100 100 Powdered carbon may also be incorporated in . an amount from 1/_>% to 3% and will increase somewhat the work-energy as well as improve the oxygen balance, but is not necessary to produce combustion in the explosive composition. Also a suitable antiacid may be added. The pelleted sodium nitrate should be more or less round in form and of substantially uniform mesh size as per following examples: ' I am aware of pelleted nitrate of sodium as such being used in explosives of the dynamite class, also the coating of ammonium nitrate pellets with trimethylal-ethyl-methane-trinitrate, and 35 also with other substances, but I am not aware of a blasting powder being heretofore produced in which each granule is a complete explosive unit in itself formed of a central kernel of sodium nitrate entirely enclosed in the fortifying, sen- 40 sitizing and ?ame supporting agents in even dissemination and in adherent relation about its (1) Minus 6 mesh, plus 8 mesh surface in proportions to make of each a sub (2) Minus 8 mesh, plus 10 mesh ‘ stantially balanced explosive unit. Nor do I know (3) Minus 10 mesh, plus 12 mesh, of any comparable powder no matter of what 45 constituted which has all of the valuable prop erties in comparison with black powder, as above set out. Percussion tests of my improved blasting pow der as above described, made under Bureau of 50 and so on up to minus 36 mesh, plus 40 mesh. - The ?ner mesh pellets are employed where in creased rate of combustion or greater brisance in the blasting powder is desired, and vice versa. This pelleted sodium nitrate is placed in a suit able tumbler or inclined rotating pellet coating bowl, and while under rotation the liquid nitro body (preferably D. N. T. or M. N. T., T. N. T.) is added to the revolving and rolling mass, prefer~ Explosives’ requirements, “Falling weight test,” gave zero results with the 8 pound weight and 7 inch drop (steel on steel anvil) and actually re quired in excess of a 12 inch drop before explosion could be induced. 55 2 araaecs Similarly, frictional impact tests as per Bureau of Mines’ requirements “Anvil friction test,” both with the ?ber and steel shoe, produced neither explosion, nor ignition-in fact no distinguish able crackling, and furthermore Bureau of Mines’ tests for fumes reported “Poisonous fumes nil.” The safety of my improved blasting powder over black powder is particularly outstanding in ignition tests, for not only‘ does the improved 10 powder withstand ignition from ordinary ?ame contact, such for instance as burning a box of matches on top of a pile of it, but it will not ignite if a teaspoonful of black powder is placed on top of a pile of it and the black powder 15 ignited. Having thus described my improved blasting composition, what I claim is: 1. A blasting powder comprising a loose mass of pellets having a sodium nitrate center coated 20 with a viscous ?lm of an explosive nitric ester lique?able at moderate temperatures forming a \binder holding an outer layer of an intimate mix ture of powdered ammonium nitrate, potassium perchlorate and powdered aluminum, so as to make each pellet a complete explosive unit. 2. A blasting powder comprising a loose mass of pellets having a sodium nitrate center coated with .a. viscous ?lm of an explosive nitric ester lique ?able at moderate temperature forming a binder holding anrouter layer of an intimate mixture of a ?nely divided explosive including a nitrate salt, a perchlorate, and an easily oxidizable metal. 3. A blasting powder comprising a loose mass of substantially uniform size pellets having a sodium nitrate center coated with a viscous ?lm of an explosive nitric ester lique?able at moderate , temperatures forming a binder holding an outer layer of an intimate mixture of a ?nely divided explosive including an oxygen yielding salt, and an easily oxidizable metal. , LAUD S. BYERS. 20
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