2005
Bridged compounds
Q 0060
Synthesis, Structure, and Derivatives of endo-4-Aminomethyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene. — Cycloaddition of endo-cyanonorbornene (I) with cy10- 062 clopentadiene
(II) provides access towards cyanotetracyclododecene derivative (III) in
excellent stereoselectivity. Compound (III) as well as a few of its derivatives are studied
spectroscopically and compared to their bicyclic analogues derived from (I). —
(KAS'YAN, L. I.; GOLODAEVA, E. A.; OKOVITYI, S. I.; KAS'YAN, A. O.;
KARPENKO, D. V.; UMRYKHINA, L. K.; Russ. J. Org. Chem. 40 (2004) 8,
1080-1091; Dnepropetrovsk State Univ., Dnepropetrovsk 320625, Ukraine; Eng.) —
Mischke