2005
Structure
D 2000
22- 007
A New Thiophosphate, Rb0.38Ag0.5Nb2PS10. — Single crystals of the title compound
are prepared by reaction of Nb, phosphorus, and sulfur in a eutectic RbI/AgI flux
(1073 K, sealed quartz tube, 72 h). Rb0.38Ag 0.5Nb 2PS 10 crystallizes in the triclinic space
group P1 with Z = 2. The structure consists of ∞1[Nb2 P S-1 0 ] chains, which are stabilized
by Ag+ ions and disordered Rb+ ions. — (DONG, Y.; KIM, S.; YUN*, H.; Acta
Crystallogr., Sect. C: Cryst. Struct. Commun. 61 (2005) 3, i25-i26; Dep. Mol. Sci.
Technol., Ajou Univ., Suwon 442-749, S. Korea; Eng.) — Schramke