2005 Cyclohexane derivatives Q 0040 Development, Scope, and Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 3-Butenyl β-Diketones. — A detailed account on previously 23- 071 published studies is presented. The title reaction provides the first examples for transition metal-catalyzed addition of an active methylene group to an unactivated olefin. — (QIAN, H.; PEI, T.; WIDENHOEFER*, R. A.; Organometallics 24 (2005) 2, 287-301; P.M. Gross Chem. Lab., Duke Univ., Durham, NC 27708, USA; Eng.) — Nuesgen
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